Product ID:AMMONIUM PYRROLIDINE DITHIOCARBAMATE, A182-10
MSDS Date:04/29/1998
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CJZQC

Emergency Phone: 201-796-7100

Info Phone: 201-796-7100

Cage: 1B464

Telephone: 201-796-7100

Cage: 1B464

1-PYRROLIDINECARBODITHIOIC ACID, AMMONIUM SALT

CAS: 5108-96-3

Fraction By Weight: 100%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: CAUSES IRRITATION. SKIN:
CAUSES IRRITATION. INGESTION: INGESTION OF LARGE AMOUNTS MAY CAUSE
GASTROINTESTINAL IRRITATION. THE TOXICOLOGICAL PROPERTIES OF THIS
SUBSTANCE HAVE NOT BEEN FULLY INVESTIGATED. INHALATION: MAY CAUSE
RESPIRATORY TRACT IRRITATION. LOW HAZARD FOR USUAL INDUSTRIAL
HANDLING. THE TOXICOLOGICAL PROPERTIES OF THIS SUBSTANCE HAVE NOT
BEEN FULLY INVESTIGATED. CHRONIC: NO INFORMATION FOUND.
Explanation of Carcinogenicity:CAS# 518-96-3: NOT LISTED BY ACGIH,
IARC, NIOSH, NTP, OR OSHA.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS,
OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: FLUSH
W/PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHILE REMOVING CONTAMD
CLOTHING & SHOES. GET MED AID IF IRRITATION DEVELOPS/PERSISTS.
WASH CLTHG BEFORE REUSE. INGEST: IF VICTIM IS CONSCIOUS & ALERT,
GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO
UNCON PERSON. GET M ED AID. INHAL: REMOVE FROM EXPOSURE TO FRESH
AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE
OXYG. GET MED AID IF COUGH/OTHER SYMPTOMS (SUPDAT)

Flash Point Method:CALC
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:IN CASE OF FIRE, USE WATER, DRY CHEMICAL, CHEMICAL
FOAM, OR ALCOHOL-RESISTANT FOAM. USE AGENT MOST APPROPRIATE TO
EXTINGUISH FIRE.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING
APPARATUS IN PRESSURE-DEMAND, NIOSH (APPROVED OR EQUIVALENT), AND
FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:DURING FIRE, IRRITATING & HIGHLY TOXIC
GASES MAY BE GENERATED BY THERMAL DECOMP/COMBUST. THIS MATL IS
SUFFICIENT QUANTITY & REDUCED PARTICLE SIZE IS CAPABLE OF CREATING
A DUST EXPLOSION.

Spill Release Procedures:GENERAL INFORMATION: USE PROPER PERSONAL
PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL
PROTECTION (SECTION 8). SPILLS/LEAKS: VACUUM/SWEEP UP MATERIAL &
PLACE INTO SUITABLE DISPOSAL CONTAINER. CLEAN UP SPILLS
IMMEDIATELY, OBSERVING PRECAUTIONS IN PROECTIVE EQUIPMENT SECTION.
AVOID GENERATING DUSTY CONDITIONS. PROVIDE VENTILATION.

Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP FROM
CONTACT WITH OXIDIZING MATERIALS. KEEP CONTAINERS TIGHTLY CLOSED.
DO NOT EXPOSE TO AIR. STORE BELOW 50C.
Other Precautions:USE WITH ADEQUATE VENTILATION. MINIMIZE DUST
GENERATION & ACCUMULATION. AVOID CONTACT W/SKIN & EYES. AVOID
INGESTION AND INHALATION: STORE PROTECTED FROM AIR. WASH CLOTHING
BEFORE REUSE.

Respiratory Protection:FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:FACILITIES STORING OR UTILIZING THIS MATERIAL SHOULD BE
EQUIPPED WITH EYEWASH FACILITY & SFTY SHOWER. USE ADEQUATE VENT TO
KEEP AIRBORNE CONCENTRATIONS LOW.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT
WITH SKIN.
Work Hygienic Practices:WASH CLOTHING BEFORE REUSE.
Supplemental Safety and Health
FIRST AID PROC: APPEAR. NOTES TO PHYS: TREAT SYMPTOMATICALLY &
SUPPORTIVELY. SARA TITLE III: IN THIS PROD ARE LISTED AS PRIORITY
POLLUTANTS UNDER CWA. NONE OF CHEMICALS IN THIS PROD ARE LISTED AS
TOXI C POLLUTANTS UNDER CWA. OSHA: NONE OF CHEMS IN PROD ARE
CONSIDERED HIGHLY HAZARDOUS BY OSHA.

Melt/Freeze Pt:=155.C, 311.F
Decomp Temp:=155.C, 311.F
Vapor Pres:NEGLIGIBLE
Solubility in Water:SOLUBLE
Appearance and Odor:YELLOW SOLID. NO ODOR REPORTED.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE. HOWEVER, MAY DECOMPOSE IF HEATED.
INCOMPATIBLE MATERIALS, EXPOSURE TO AIR. TEMPERATURES ABOVE 55C.
Hazardous Decomposition Products:NITROGEN OXIDES, CARBON MONOXIDE,
OXIDES OF SULFUR, CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAX CONC OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOX REFERENCE
LEVELS: NONE LISTED. RCRA F, P, & U SERIES: NONE LISTED.

Toxicological Information:RTECS#: CAS# 5108-96-3 UNLISTED. LD50/LC50:
NOT AVAILABLE. EPIDEMIOLOGY, TERATOGENICITY, REPRODUCTIVE EFFECTS,
NEUROTOXICITY, MUTAGENICITY: NO INFORMATION FOUND. OTHER STUDIES:
NO DATA AVAILABLE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:EXOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL OR OTHER:
NOT AVAILABLE.

Transport Information:NO INFORMATION AVAILABLE.

SARA Title III Information:SECTION 12B: NONE OF CHEMS ARE LISTED UNDER
TSCA SECTION 12B. SEFTION 302(RQ): NONE OF CHEMS IN MATL HAVE RQ.
SECTION 302 (TPQ): NONE OF CHEMS IN PROD HAVE A TPQ. SARA CODES:
CAS# 5108-96-3: ACUTE, CH RONIC . SECTION 313: NO CHEMS ARE
REPORTABLE. CLEAN AIR ACT: THIS MATL DOES NOT CNTN ANY HAZ AIR
POLLUTANTS. THIS MATL DOES NT CNTN ANY CLASS 1 OZONE DEPLETORS.
THIS MATL DOES NOT CNTN ANY CLASS 2 OZO NE DEPLETORS. OSHA: NONE OF
CHEMS IN PROD ARE LISTED AS HAZ SUBSTANCES UNDER CWA. ONE OF CHEMS
IN PROD ARE LSITED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF
CHEMICALS (SUPDAT)
Federal Regulatory Information:EUROPEAN/INTERNATIONAL REGULATIONS.
EUROPEAN LABELING IN ACCORDANCE WITH EC DIRECTIVE. HAZARD SYMBOLS:
XI. RISK PHRASES: R 36/38 IRRITATING TO EYES AND SKIN. SAFETY
PHRASES: S 24/25 AVOID CONTACT WITH SKIN AND EYES. WGK(WATER
DANGER/PROTECTION). CAS # 5108-96-3: NO INFORMATION FOUND. CANADA
CAS# 5108-96-3 IS LISTED ON CANADA'S DSL/NDSL LIST. THIS PRODUCT
HAS WHMIS CLASSIFICATION OF D2B. CAS# 5108- 96-3 IS NOT LISTED ON
CANADA'S INGREDIENT DISCLOSURE LIST.
State Regulatory Information:CAS# 5108-96-3 IS NOT PRESENT ON STATE
LISTS FROM CA, PA, MN, MA, FL, OR NJ. CALIFORNIA NO SIGNIFICANT
RISK LEVEL: NONE OF CHEMICALS IN THIS PRODUCT ARE LISTED.